Accuracy of various molecular weight determination methods.

 

  Standard Error of Estimate
Mw by LALLS  molecular weight above 50,000 +/- 5 to 10 %
Mw by LALLS  molecular weight below 50,000 +/- 10 to 15 %
Mn by LALLS +/  20 to 30 %
   
Mw by MALLS  molecular weight above 100,000 +/- 3 to 10 %
Mw by MALLS  molecular weight below 100,000 +/- 10 to 15 %
Mn by MALLS +/  20 to 30 %
   
Mn by Membrane Osmometry MW above 50,000 +/- 5 to 10 %
   
Mn by Vapor Pressure Osmometry MW 15,000 - 30,000 +/- 10 to 15 %
Mn by Vapor Pressure Osmometry Mw belo15.000 +/- 2 to 5%
   
Mw by GPC/SEC +/- 3 to 10 %
Mn by GPC/SEC +/- 10 to 15 %
Mz by GPC/SEC +/- 10 to 15 %
Mp by GPC/SEC +/- 3 to 10 %
   
Mw by GPC/DV   Universal Calibration +/- 5 to 10 %
Mn by GPC/DV   Universal Calibration +/- 10 to 15 %
Mz by GPC/DV   Universal Calibration +/- 10 to 15 %
Mp by GPC/DV   Universal Calibration +/- 5 to 10 %
   
Mn by End group analysis MW Below 10,000 +/- 10 to 15 %
   
Mz by Ultra centrifuge Mw above 100,000 +/- 10 to 15 %
   
Mv by Viscotek viscometer Y-501C +/- 5 to 10 %
   
Intrinsic Viscosity by Viscosity Y-501C +/- 5 to 10 %

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